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Pikachu meets the Pichu brothers and goes on an adventure through the city with them while trying to get back to the building where the rest of Ash's Pokémon are.
AnimeLok is the best site to watch Pokémon: Pikachu and Pichu SUB online, or you can even watch Pokémon: Pikachu and Pichu DUB in HD quality. You can also find Sunrise anime on AnimeLok website.
